Enhancing performance of molybdenum doped strontium ferrite electrode by surface modification through Ni infiltration

نویسندگان

چکیده

Molybdenum doped strontium ferrite, Sr2Fe1.5O0.5O6 (SFM), is a promising perovskite-type hydrogen electrode material in solid oxide cells (SOCs), but usually suffers from insufficient electro-catalytic activity. Herein, Ni nanoparticles with high properties have been infiltrated into SFM scaffold to form Ni-SFM activity for power generation and CO2 electro-reduction. Pre-sintering temperature loading of electrodes systematically investigated minimize the polarization resistance (Rp). Rps bare vary significantly pre-sintering temperature, lowest Rp value 1.04?cm2 obtained pre-fired at 1050 °C. Moreover, reduced 0.32?cm2 achieved 800 °C after infiltration. Additionally, three-dimensional microstructure simulated numerically, geometric including Ni/SFM/gas triple-phase-boundaries (TPBs) length, Ni/SFM interfacial area, surface area are calculated under various loadings correlate performance, revealing that performance strongly affected not only by TPBs also interface area. Enhanced electrochemical indicate high-performance SOCs application.

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ژورنال

عنوان ژورنال: International Journal of Hydrogen Energy

سال: 2021

ISSN: ['0360-3199', '1879-3487']

DOI: https://doi.org/10.1016/j.ijhydene.2020.12.185